• First emission studies of Tc2X82- systems (X = Cl, Br)
    B.N. Briggs, D.R. McMillin, T.K. Todorova, L. Gagliardi, F. Poineau, K.R. Czerwinski and A.P. Sattelberger
    Dalton Transactions, 39 (2010), p11322-11324
    DOI:10.1039/C0DT00751J | unige:14694 | Abstract | Article HTML | Article PDF
The emission spectra of the solids [n-Bu4N]2Tc2X8 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the 1δ–δ* excited state, as with the rhenium homologues, but has a shorter lifetime.

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