First emission studies of Tc
2
X
8
2-
systems (X = Cl, Br)
B.N. Briggs, D.R. McMillin, T.K. Todorova, L. Gagliardi, F. Poineau, K.R. Czerwinski and A.P. Sattelberger
Dalton Transactions
,
39
(2010), p11322-11324
DOI:
10.1039/C0DT00751J
|
unige:14694
|
Abstract
|
Article HTML
|
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The emission spectra of the solids [
n
-Bu
4
N]
2
Tc
2
X
8
 (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in theÂ
1
δ–δ* excited state, as with the rhenium homologues, but has a shorter lifetime.
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